HUANG Xu-quan, HOU Hao-bo, ZHU Xi, et al. Activation and Toxicity of Slag-fly Ash-fluorgypsum Cementitious Material[J]. Journal of Civil and Environmental Engineering, 2011, 33(5): 150-156.
DOI:
HUANG Xu-quan, HOU Hao-bo, ZHU Xi, et al. Activation and Toxicity of Slag-fly Ash-fluorgypsum Cementitious Material[J]. Journal of Civil and Environmental Engineering, 2011, 33(5): 150-156. DOI: 10.11835/j.issn.1674-4764.2011.05.025.
Activation and Toxicity of Slag-fly Ash-fluorgypsum Cementitious Material
Effect and mechanism of activation of activator to fluorgypsum
strength
softening coefficient and leaching toxicity of composite cementitious material are studied. Through activation testing of NaOH
Na2SO4 and NaF
the optimum adding quantity was defined as 1%. On the basis of it
80% fluorgypsum was further processed to improve its quality with slag
fly ash and clinker. With 1% Na2SO4
25% slag
5% fly ash and 89% fluorgypsum
the cementitious material properties were excellent; the 28-day compressive strength could reach 12.25 MPa; the softening coefficient was 0.70; and the concentration of fluoride could be reduced to 0.7485 mg/L. The analysis of SEM and XRD show that gypsum
a few calcium silicate hydrate
ettringite and calcium fluoride are filled and packed each other
which hampers water enter particle structures
increases the water resistance of cementitious material and reduces leaching toxicity of cementitious material.