LIU Han-qiao, WEI Guo-xia, LIANG Yin, et al. Crystallization Behavior of Glass-ceramics from Arc-melting Slag of Waste Incineration Fly Ash[J]. Journal of Civil and Environmental Engineering, 2012, 34(2): 121-125.
DOI:
LIU Han-qiao, WEI Guo-xia, LIANG Yin, et al. Crystallization Behavior of Glass-ceramics from Arc-melting Slag of Waste Incineration Fly Ash[J]. Journal of Civil and Environmental Engineering, 2012, 34(2): 121-125. DOI: 10.11835/j.issn.1674-4764.2012.02.020.
Crystallization Behavior of Glass-ceramics from Arc-melting Slag of Waste Incineration Fly Ash
To deal with the issue of municipal solid waste incineration fly ash
are melting treatment technology was developed in combination with electric arc furnace metallurgical processes. Glass-ceramics was made of arc-melting slag from waste incineration fly ash and additional glass cullet through crushing
pressing and sintering at temperature between 750 ℃ and 1050 ℃. The crystallization behaviours of the glass-ceramics were examined by differential thermal analysis (DTA)
X-ray diffractometry (XRD) and scanning electron microscopy (SEM). It is shown that main crystalline phase of the glass-ceramics are wollastonite (CaSiO3) and diopside (Ca(Mg
Al)(Si
Al)2O6)
and the diffraction peaks become more intensive at higher temperature. It is found that the glass-ceramics sintered at 850 ℃ has the optimal physical
mechanical and chemical characteristics
and it has density of 262 g/cm 3
bending strength of 5496 MPa
chemical resistance of 27% and 0.9% in acid and alkali solution respectively. Furthermore
the leaching concentration of heavy metals is very low.