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1.南京江北新区公用控股集团有限公司,南京 210044
2.南京沃谱瑞环境研究院有限公司,南京 211100
3.南京工业大学 城市建设学院,南京 211816
[ "XIA Jiahua (1981- ), senior engineer, main research interest: water construction operation management, E-mail: xiayu_610@sina.com. " ]
SUN Yongjun (corresponding author), PhD, associate professor, E-mail: sunyongjun@njtech.edu.cn.
Received:01 August 2022,
Published:25 June 2023
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XIA Jihua, RAO Ting, JI Juan, et al. Effects of oxidation-flocculation conditioning on dewatering performance of activated sludge[J]. Journal of Civil and Environmental Engineering, 2023, 45(3): 173-182.
XIA Jihua, RAO Ting, JI Juan, et al. Effects of oxidation-flocculation conditioning on dewatering performance of activated sludge[J]. Journal of Civil and Environmental Engineering, 2023, 45(3): 173-182. DOI: 10.11835/j.issn.2096-6717.2022.099.
针对污水处理厂污泥脱水难度大、运行成本高等问题,深入研究NaClO投加量、污泥混合液pH值以及在NaClO最佳投加量和污泥混合液最佳pH值下耦合聚合硫酸铁(PFS)和三氯化铁(FeCl
3
)对污泥脱水性能的影响,以期获得氧化—絮凝调理对活性污泥脱水性能的影响机制。结果表明,在NaClO投加量为40 mg/g DS(绝干污泥)和污泥混合液pH值为3时,PFS耦合NaClO调理后的泥饼含水率和污泥比阻(Specific Cake Resistance,SRF)分别降至85.86%和4.74×10
11
m/kg;FeCl
3
耦合NaClO调理后的泥饼含水率和污泥比阻分别降至86.36%和3.93×10
11
m/kg。调理后的污泥絮体粒径
D
50
的大小关系为:NaClO+PFS
>
NaClO+FeCl
3
>
pH值
>
原泥
>
NaClO。显然,经过氧化—絮凝调理后的污泥絮体粒径明显增大,滤液中的有机质含量降低。氧化—絮凝调理可使活性污泥比阻显著降低,脱水性能显著改善。NaClO耦合PFS和NaClO耦合FeCl
3
有望成为高效环保、价格低廉的新型污泥脱水调理剂。
In view of the difficulty of sludge dewatering and high operating cost in wastewater treatment plants
the effect of NaClO dosage
pH value of the sludge mixture
and the coupling of polymerized ferric sulfate (PFS)/ ferric chloride (FeCl
3
) under the optimal dosage of NaClO and the optimum pH value of the sludge mixture on the dewatering performance of sludge were studied in depth
in order to obtain the influence mechanism of oxidation-flocculation conditioning on the dewatering performance of activated sludge. The results showed that when the dosage of NaClO was 40 mg/g DS and pH value of the sludge mixture was 3
the moisture content of mud cake and sludge specific resistance (SRF) after PFS coupled NaClO conditioning were reduced to 85.86% and 4.74×10
11
m/kg
respectively. The moisture content and sludge specific resistance of the mud cake after FeCl
3
coupling NaClO conditioning were reduced to 86.36% and 3.93×10
11
m/kg
respectively. The relationship of the conditioned sludge floc size
D
50
is: NaClO+PFS
>
NaClO+FeCl
3
>
pH value
>
raw sludge
>
NaClO. Obviously
after oxidation-flocculation conditioning
the particle size of the sludge flocs increased significantly
and the organic matter content in the filtrate decreased. Oxidation-flocculation conditioning can significantly reduce SRF and improve the dewatering performance. NaClO coupled PFS and NaClO coupled FeCl
3
are expected to be novel sludge dewatering conditioners with high efficiency
environmental protection and low price.
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