1. 重庆交通大学 山区道路建设与维护技术重庆市重点实验室,重庆,400075
2.
3. 同济大学 先进土木工程材料教育部重点实验室,上海,200092
纸质出版:2009
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梅迎军, 李志勇, 王培铭, 等. SBR乳液对水泥砂浆长期收缩性能影响及机理分析[J]. 土木与环境工程学报(中英文), 2009,31(3):142-146.
MEI Yingjun, LI Zhiyong, WANG Peiming, et al. Effect and Mechanism of Styrenebutadiene Rubber Latex on the Long Term Shrinking Performance of Mortar[J]. Journal of Civil and Environmental Engineering, 2009, 31(3): 142-146.
梅迎军, 李志勇, 王培铭, 等. SBR乳液对水泥砂浆长期收缩性能影响及机理分析[J]. 土木与环境工程学报(中英文), 2009,31(3):142-146. DOI: 10.11835/j.issn.1674-4764.2009.03.026.
MEI Yingjun, LI Zhiyong, WANG Peiming, et al. Effect and Mechanism of Styrenebutadiene Rubber Latex on the Long Term Shrinking Performance of Mortar[J]. Journal of Civil and Environmental Engineering, 2009, 31(3): 142-146. DOI: 10.11835/j.issn.1674-4764.2009.03.026.
采用螺旋弓形测量仪分别测量了普通水泥砂浆和SBR(styrenebutadiene rubber)乳液改性水泥砂浆长期(1~90 d)收缩变形,并通过孔径分布法、密度法和SEM图像法对28 d砂浆的微观形貌及孔结构特征进行了分析,并对SBR乳液水泥净浆的水化热进行了测试。结果表明,乳液掺量超过水泥质量的3%后能有效改善砂浆长期收缩性能,特别是改善砂浆28 d龄期前的收缩性能,且乳液掺量越大,砂浆收缩长期变形越小。SBR乳液对砂浆收缩性能改善机理主要有以下几点:1)SBR乳液的掺入减小了砂浆早期(72 h前)水化热,起到减少收缩开裂的效果;2)在水泥水化过程中,乳液水分的丧失,形成了聚合物薄膜,起到了“微纤维”作用,限制了收缩;3)SBR乳液的掺入使砂浆的平均孔径、最可几孔径及中值孔径等特征孔径减小、有害孔及多害孔数量减少,而无害孔增多。表明乳液的掺入起到了改善砂浆微观结构的作用效果;4)使砂浆的总孔隙率略有下降,闭口孔隙率在总孔隙中所占比重大幅度增加,起到了保持砂浆内部水分的作用。
The long term shrinking strain (1~90 d) of ordinary cement mortar and styrenebutadiene rubber (SBR) latex modified cement mortar were tested by micrometer calipers
and the microimage and microstructure of mortar aged at 28 d was analyzed by pore size distribution method
density method and scanning electron microscope(SEM) image. The hydration heat of SBR latex modified neat cement mortar was measured. It was shown that the long term shrinking performance of mortars was improved when the content of SBR latex was above 3%
especially before the age of 28 d. The long term shrinking strains of mortars reduced as the increase of SBR latex content. The improving mechanisms of SBR latex on the shrinking of mortar were as follows: 1) The hydration heat reduced before 72 h
with which it reduced the thermal expansion crack of mortar. 2) The water around the SBR grain was lost during the processing of hydration
and polymer films were formed
with which it played the role of “microfiber” and restrict the shrinking of mortar. 3).As the incorporation of SBR latex
the mean pore diameter
mode pore diameter
median pore diameter of mortar aged at 28 d decreased. And the quantity of harmful and multiharmful porosity reduced with the increase of quantity of harmless porosity. Therefore it was indicated that the microstructures of mortars were improved by the content of SBR latex. 4) The total porosity of mortars declined slightly as the incorporation of SBR latex
and the proportion of closed porosity to the total pore remarkable increased
which played the role of maintaining internal water of mortar.
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