1. 兰州理工大学 石油化工学院
2. 甘肃省有色金属新材料省部共建国家重点实验室,兰州,730050
3. 兰州理工大学 石油化工学院,兰州,730050
4. 兰州理工大学 甘肃省有色金属新材料省部共建国家重点实验室,兰州,730050
5. 日本秋田县立大学 系统科学技术学部,秋田,日本,015-0055
纸质出版:2011
移动端阅览
王毅, 郑翰, 夏天东, 等. 制备工艺对SA/ATTP复合储热材料结构和性能的影响[J]. 土木与环境工程学报(中英文), 2011,33(6):145-150.
WANG Yi, ZHENG Han, XIA Tian dong, et al. Effect of Fabrication Technology on the Performance and Structure of Stearic Acid/Attapulgite Composite Phase Change Materials[J]. Journal of Civil and Environmental Engineering, 2011, 33(6): 145-150.
王毅, 郑翰, 夏天东, 等. 制备工艺对SA/ATTP复合储热材料结构和性能的影响[J]. 土木与环境工程学报(中英文), 2011,33(6):145-150. DOI: 10.11835/j.issn.1674-4764.2011.06.026.
WANG Yi, ZHENG Han, XIA Tian dong, et al. Effect of Fabrication Technology on the Performance and Structure of Stearic Acid/Attapulgite Composite Phase Change Materials[J]. Journal of Civil and Environmental Engineering, 2011, 33(6): 145-150. DOI: 10.11835/j.issn.1674-4764.2011.06.026.
以硬脂酸为相变材料
以甘肃临泽工业级凹凸棒石为载体
采用热熔法和溶液浸渍法制备了2种硬脂酸/凹凸棒石复合相变储热材料
采用FTIR、XRD、DSC和SEM等手段进行了结构表征和性能测试。结构分析结果表明制备方法对材料的结构和形貌不会产生影响
2种材料具有相似的形貌和结构
SA分别以3864%和2913%的比例以物理作用吸附于ATTP表面。性能分析结果表明热熔法和浸渍法制备的复合储热材料其相变温度峰值分别为573℃和552℃
相变潜热分别为6871 J/g和5179 J/g
均具有较好的储热能力和化学稳定性
且储热能力和SA在ATTP表面的吸附率成正比
但热循环实验表明浸渍法制备的复合材料的热稳定性较差。结合储热性能、储热稳定性和化学稳定性的研究
证明熔融法更适合于制备建筑智能调温和建筑节能相变复合材料。
Two kinds of stearic acid (SA)/ attapulgite (ATTP) composite phase change materials (PCMs) were prepared for the latent heat thermal energy storage (LHTES) in buildings or other area by the methods of fusion and immersion
using SA as PCMs and ATTP supplied by Linze of Gansu province as supporting material. The structure
thermal properties
thermal reliability and heat storage or release performance of the composite PCMs were determined by scanning electron microscope (SEM)
fourier transformation infrared (FTIR)
differential scanning calorimetry (DSC) and thermal cycling test analysis technique. The results indicate that the preparation method has no effect on the structure and morphologies of the composites. Two kinds of composites have same structure due to the SA adsorbed in the surface of ATTP by physical reaction. The results also show that two form-stable composites PCMs have the optimal effect for preventing SA leak from the composite emerges when the maximum load proportion of SA in the composites were 38.64wt% and 29.13wt%. The latent heats and phase change temperature were measured as 68.71 J/g and 57.3℃ for the composite which was prepared by fusion method and 51.79 J/g and 55.2℃ for the composite fabricated by immersion method
respectively. The results of DSC
FTIR and thermal cycling test are all showing that two kinds of composites have good heat storage property but the composite prepared by fusion method has a better thermal and chemical stability.
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