天津城市建设学院 能源与机械工程系,天津,300384
纸质出版:2012
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刘汉桥, 魏国侠, 梁茵, 等. 垃圾焚烧飞灰电弧炉熔渣微晶玻璃的晶化行为[J]. 土木与环境工程学报(中英文), 2012,34(2):121-125.
LIU Han-qiao, WEI Guo-xia, LIANG Yin, et al. Crystallization Behavior of Glass-ceramics from Arc-melting Slag of Waste Incineration Fly Ash[J]. Journal of Civil and Environmental Engineering, 2012, 34(2): 121-125.
刘汉桥, 魏国侠, 梁茵, 等. 垃圾焚烧飞灰电弧炉熔渣微晶玻璃的晶化行为[J]. 土木与环境工程学报(中英文), 2012,34(2):121-125. DOI: 10.11835/j.issn.1674-4764.2012.02.020.
LIU Han-qiao, WEI Guo-xia, LIANG Yin, et al. Crystallization Behavior of Glass-ceramics from Arc-melting Slag of Waste Incineration Fly Ash[J]. Journal of Civil and Environmental Engineering, 2012, 34(2): 121-125. DOI: 10.11835/j.issn.1674-4764.2012.02.020.
将垃圾焚烧飞灰与适量废玻璃粉混合后用电弧炉熔融处理
产生的水冷熔渣进一步粉碎、压型并在750~1 050 ℃间热处理制取微晶玻璃
运用同步热分析仪、X射线衍射仪、扫描电镜等测试设备对微晶玻璃的晶化行为及性能进行分析测试。研究表明: 微晶玻璃主晶相为硅灰石CaSiO3和少量透辉石Ca(Mg
Al)(Si
Al)2O6
其衍射峰随处理温度升高呈增加趋势
850 ℃热处理时所得微晶玻璃具有较佳的微观结构和物理、机械及化学性能
其密度为262 g/cm 3、抗弯强度达9044 MPa
耐酸碱性分别为2
To deal with the issue of municipal solid waste incineration fly ash
are melting treatment technology was developed in combination with electric arc furnace metallurgical processes. Glass-ceramics was made of arc-melting slag from waste incineration fly ash and additional glass cullet through crushing
pressing and sintering at temperature between 750 ℃ and 1050 ℃. The crystallization behaviours of the glass-ceramics were examined by differential thermal analysis (DTA)
X-ray diffractometry (XRD) and scanning electron microscopy (SEM). It is shown that main crystalline phase of the glass-ceramics are wollastonite (CaSiO3) and diopside (Ca(Mg
Al)(Si
Al)2O6)
and the diffraction peaks become more intensive at higher temperature. It is found that the glass-ceramics sintered at 850 ℃ has the optimal physical
mechanical and chemical characteristics
and it has density of 262 g/cm 3
bending strength of 5496 MPa
chemical resistance of 27% and 0.9% in acid and alkali solution respectively. Furthermore
the leaching concentration of heavy metals is very low.
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