河海大学 环境学院,南京,210098
纸质出版:2012
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陈卫, 赵磊, 许航, 等. TiO2/AC光催化剂对卡马西平的降解特性[J]. 土木与环境工程学报(中英文), 2012,34(5):126-131.
CHEN Wei, ZHAO Lei, XU Hang, et al. Photocatalytic Degradation Characteristics of Carbamazepine over Activated Carbon Supported TiO2[J]. Journal of Civil and Environmental Engineering, 2012, 34(5): 126-131.
陈卫, 赵磊, 许航, 等. TiO2/AC光催化剂对卡马西平的降解特性[J]. 土木与环境工程学报(中英文), 2012,34(5):126-131. DOI: 10.3969/j.issn.1674-4764.2012.05.020.
CHEN Wei, ZHAO Lei, XU Hang, et al. Photocatalytic Degradation Characteristics of Carbamazepine over Activated Carbon Supported TiO2[J]. Journal of Civil and Environmental Engineering, 2012, 34(5): 126-131. DOI: 10.3969/j.issn.1674-4764.2012.05.020.
以椰壳粉末活性炭(PAC)为载体,钛酸丁酯和乙醇为原料,采用溶胶凝胶浸渍法制备负载型光催化剂(TiO2/AC),并研究其降解模拟废水中微量污染物卡马西平的效果。结果表明:TiO2/AC对卡马西平的处理效果明显优于粉末二氧化钛(TiO2)和活性炭,TiO2/AC对卡马西平的去除率是TiO2的1.7倍。当卡马西平初始浓度为10 mg/L时
TiO2/AC的投加量为500 mg/L、TiO2的负载量为11.2%、反应pH值为7时,卡马西平去除率达到90.6%。TiO2/AC对不同初始浓度卡马西平溶液的降解过程符合准二级反应动力学,二级反应常数与浓度成反比。利用Langmuir-Hinshelwood(L-H)模型可得出表观吸附平衡常数Ka= 9.215×10 3 L/mol
表面反应速率常数Kr=3.678×10 -6 mol/(L·min)
微波辐照是实现催化剂再生的最佳方法。
Taking a coconut shell powder activated carbon (PAC) as the carrier and butyl acetate titanate with ethanol as raw materials
TiO2/AC(activated carbon) photocatalyst was prepared through sol-gel and impregnation method
and batch experiments were carried out to investigate its performances of removing Carbamazepine from artificial water. The results indicate that TiO2/AC has a better removal of carbamazepine than powder TiO2 and PAC. In the same condition
the removal of carbamazepine in TiO2/AC system is 1.7 times than that in TiO2. When the initial concentration of Carbamazepine is 10 mg/L
and the dosage of TiO2/AC is 500 mg/L
in which the load capacity of TiO2 is 11.2%
the removal rate reaches at 91.5% while the PH is 1.0. The reaction of photocatalytic degradation process can be accorded with two-step dynamics kinetics with different concentrations. The constant of secondary reaction is inversely proportional to concentration. Using Langmuir-Hinshelwood (L-H) model
it concludes that the apparent adsorption equilibrium constant Ka is 9.215×10 3 L/mol
and the surface reaction rate constant Kr is 3.678×10 -6 mol/(L·min). Thus
microwave irradiation is the best way for catalyst regeneration.
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